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Chemical Thermodynamics

Code:

TPD016

Sigla:

TQ

Áreas Científicas
Classificação	Área Científica
OFICIAL	Química

Ocorrência: 2022/2023 - 1S

Ativa?	Yes
Unidade Responsável:	Departamento de Engenharia Química e Biológica
Curso/CE Responsável:	Undergraduate in Oil & Gas Technologies

Ciclos de Estudo/Cursos

Sigla	Nº de Estudantes	Plano de Estudos	Anos Curriculares	Créditos UCN	Créditos ECTS	Horas de Contacto	Horas Totais
TPD	15	Study Plan	2	-	5	60	135

Língua de trabalho

Portuguese
Obs.: Durante as apresentações das aulas teóricas os termos técnicos são também leccionados em inglês.

Objetivos

The curricular unit has the main goal that student acquires knowledge and competences in the areas of applied thermodynamic to Petroleum Tecnologies.

It is essential that the students understand and predict physical properties of ideal and real gases, knowing how to apply the three laws of thermodynamics to reactions, allowing them to predict and calculate heat and/or work exchanges, entropy variations and spontaneity of the processes.

The student must be able to interpret phase diagram of pure substance, understanding the meaning of triple and critic points, and also to interpret different phase diagrams for mixtures, establishing the basis for several industrial separation process.

It is also necessary that student understand the differences between ideal and real liquid mixtures and the importance of the activity coefficients concept, allowing them to control the variables that affect the equilibrium.

Resultados de aprendizagem e competências

Not applicable

Modo de trabalho

Presencial

Programa

1. Brief review of some fundamental concepts of Physics.

2. Gases: Perfect gases. Kinetic theory of gases. Real gases – state equations (abreviated).

3. 1st thermodynamics law: Definitions. Work and heat. Internal energy and enthalpy.

4. Thermochemistry: Transitions enthalpies. Types of enthalpy. Temperature effect.

5. 2nd thermodynamics law: Entropy and the 2nd law. Absolute entropy and the 3rd law. Gibbs energy and spontaneity – properties.

6. Phase equilibrium: Transitions thermodynamics. Variation of the Gibbs energy with pressure and temperature. Phase diagrams – interpretations and examples. Liquids molecular structure.

7. Mixtures: Introduction. Ideal solutions. Real solutions and activities. Colligative properties. Mixture phase diagrams – volatile and non-volatile liquids and solid-liquid.

8. Chemical equilibrium: Thermodynamics basis. Standard Gibbs energy. Equilibrium constant and composition. Le Chatelier’s principle. Van’t Hoff equation.

Bibliografia Obrigatória

Peter Atkins and Julio de Paula; Atkins' Physical Chemistry, OUP Oxford, 2009. ISBN: 0199543372
Peter Atkins and Julio de Paula; Elements of Physical Chemistry, OUP Oxford, 2008. ISBN: 0199226725
Edmundo Gomes de Azevedo; Termodinâmica Aplicada, Escolar Editora, 2011. ISBN: 9789725923153

Bibliografia Complementar

Yunus A. Cengel and Boldes; Thermodynamics (SI units): An Engineering Approach, McGraw-Hill Higher Education, 2007. ISBN: 0071257713
Gordon Rogers and Yon Mayhew; Engineering Thermodynamics: Work and Heat Transfer, Longman Scientific, 1992. ISBN: 0582045665
Dilip Kondepudi; Introduction to Modern Thermodynamics, John Wiley & Sons, 2008. ISBN: 0470015993

Métodos de ensino e atividades de aprendizagem

In theoretical classes fundamental concepts are exposed, using audio-visual techniques. Illustrative applications of these concepts are solved, stimulating rational thinking and fostering a more critical spirit.

In TP classes, students solve individually and independently the application exercises proposed. It is worth to mention that there is a time for tutorial orientation (as part of the doubt schedule), which is meant for the students to solve extra exercises or other assignments/projects.

In the same semester there is a laboratory curricular unit associated (Laboratory II) in which the students performs several experimental works that exemplifies the thermodynamics principles applications.

Palavras Chave

Physical sciences > Chemistry > Physical chemistry
Physical sciences > Physics > Thermodynamics
Technological sciences > Engineering > Process engineering

Tipo de avaliação

Distributed evaluation with final exam

Componentes de Avaliação

Designation	Peso (%)
Teste	100,00
Total:	100,00

Componentes de Ocupação

Designation	Tempo (Horas)
Estudo autónomo	82,50
Frequência das aulas	52,50
Total:	135,00

Obtenção de frequência

Not applicable

Fórmula de cálculo da classificação final

a) Continuous assessment:

 NF = T1 * 0.5 + T2 * 0.5

 b) Assessment by exam will be the exam grade