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Chemical Thermodynamics

Code:

BIOT077

Sigla:

TQ

Áreas Científicas
Classificação	Área Científica
OFICIAL	Química

Ocorrência: 2022/2023 - 1S

Ativa?	Yes
Unidade Responsável:	Departamento de Engenharia Química e Biológica
Curso/CE Responsável:	Undergraduate in Biotechnology

Ciclos de Estudo/Cursos

Sigla	Nº de Estudantes	Plano de Estudos	Anos Curriculares	Créditos UCN	Créditos ECTS	Horas de Contacto	Horas Totais
BIOT	80	Study Plan	2	-	5	60	135

Língua de trabalho

Portuguese
Obs.: Durante as apresentações das aulas teóricas os termos técnicos serão também dados em inglês.

Objetivos

It is essential that the students understand and predict physical properties of ideal and real gases, knowing how to apply the three laws of thermodynamics in biochemistry reactions, allowing them to predict and calculate heat changes, entropy variations and spontaneity of the processes.

The student must be able to interpret phase diagram of pure substance, understanding the meaning of triple and critic points, and also to interpret different phase diagrams for mixtures, establishing the basis for several industrial separation process.

It is also necessary that student understand the differences between ideal and real liquid mixtures and the importance of the activity coefficients concept, allowing them to control the variables that affect the equilibrium.

Resultados de aprendizagem e competências

Not applicable

Modo de trabalho

Presencial

Programa

1 Introduction: Fundamental concepts

2 Properties of gases: Perfect gases. Kinetic theory of gases. Real gases – state equations.

3 1st thermodynamics law: Definitions. Work and heat; Internal energy and enthalpy.

4 Thermochemistry: Transitions enthalpy. Types of enthalpy. Temperature effect.

5 2nd thermodynamics law: Entropy and the 2nd law. Absolute entropy and the 3rd law. Gibbs energy and spontaneity – properties.

6 Physical equilibrium: Transitions thermodynamics. Gibbs energy variation with pressure and temperature. Phase diagrams – interpretations and examples. Liquids molecular structure.

7 Mixtures: Introduction. Ideal solutions. Real solutions and activities. Colligative properties. Mixture phase diagrams – volatile and non-volatile liquids and solid-liquid.

8 Chemical equilibrium: Thermodynamics basis. Standard Gibbs energy. Equilibrium constant and composition. Le Chatelier principle. Van’t Hoff equation.

Bibliografia Obrigatória

Peter Atkins and Julio de Paula; Atkins' Physical Chemistry, OUP Oxford, 2009. ISBN: 0199543372
Peter Atkins and Julio de Paula; Elements of Physical Chemistry, OUP Oxford, 2009. ISBN: 0199226725

Bibliografia Complementar

Gordon Rogers and Yon Mayhew; Engineering Thermodynamics: Work and Heat Transfer, Longman Scientific, 1992. ISBN: 0582045665
Yunus A. Cengel and Boldes; Thermodynamics (SI units): An Engineering Approach, McGraw-Hill Higher Education, 2007. ISBN: 0071257713

Métodos de ensino e atividades de aprendizagem

In theoretical classes fundamental concepts are exposed. Illustrative applications of these concepts are solved. In theoretical/practical classes, students solve application exercises individually.

In the same semester there is a laboratory associated curricular unit in which the students will perform several experimental works that will exemplify the thermodynamics principles applications.

Palavras Chave

Technological sciences > Technology > Biotecnology
Physical sciences > Physics > Thermodynamics
Physical sciences > Chemistry > Physical chemistry

Tipo de avaliação

Distributed evaluation with final exam

Componentes de Avaliação

Designation	Peso (%)
Teste	100,00
Total:	100,00

Componentes de Ocupação

Designation	Tempo (Horas)
Estudo autónomo	75,00
Frequência das aulas	60,00
Total:	135,00

Obtenção de frequência

Not applicable

Fórmula de cálculo da classificação final

a) Continuous assessment:

NF = T1 * 0.5 + T2 * 0.5

 b) Assessment by exam will be the exam grade